There isn't a way for you to target a specific core, however the scheduler will handle starting up one task (or MPI rank) on each core for you.
If your applicatin is truly "embarssingly parallel" you may not want to use MPI at all. You can simply submit a job with multiple tasks (each of which is an instance of your application).
For example, "job submit /parametric:1-1000 myapp.exe" will run your appliaction 1000 times, with one active process per core in the cluster at any time.
I recommend you check out our docs for more details:
http://technet.microsoft.com/en-us/library/cc719020(WS.10).aspxTHanks,
Josh
-Josh