You're off topic for this forum, which is dedicated to Windows Live OneCare.
Note that POP access for Hotmail accounts is only valid for a paid account.
Servers tab settings:
Incoming mail: pop3.live.com
Outgoing mail: smtp.live.com
Account name: Your e-mail address (name@live.com)
Password: Your password
Log on using Secure Password Authentication: Not checked
My server required authentication: Checked (Important!)
Advanced tab settings:
Outgoing mail: 25
SSL Connection: Checked
-steve