Microsoft certification exams measure your knowledge of a technology so if you don’t have any experience with .Net, you will unlikely pass the exam just by reading the training kit.
If I saw an applicant with no (or little) .Net experience however they had passed a .Net exam, probably wouldn't hire them. if I did hire them, they would get a very junior role.
Based on this, passing this exam would not make you resume stronger.
Jeff Wharton MSysDev (C.Sturt), MDbDsgnMgt (C.Sturt) MCT, MCPD, MCITP, MCDBA, MCSD, MCAD