Hi,
I think the main target should be the MCPD. You could look at
http://www.microsoft.com/learning/en/us/certification/cert-vstudio.aspx.
If you go for the Visual Studio 2010 exams, then you should start with the ASP.Net one (70-515), where you already have experience and where the self-paced training kit is already available.
There is no real order required. You can do them in any order. I would just do the PRO exam at the end.
With kind regards,
Konrad