You can get started with one of these exams
http://www.microsoft.com/learning/en/us/certification/cert-vstudio.aspx#tab2
but if the exam says you need atleast 2 years of professional experience. If you are new, you can see the topics for each exam and then prepare them with MSDN articles and books.
As long as you are comfortable with the topics, you should be good to go. You can start with Web or Windows whichever you are more familiar with..
Rakesh