Hi davidstlyoui,
Do you use the VS2013?
Based on this document here:
https://msdn.microsoft.com/en-us/library/hh873207.aspx?f=255&MSPPError=-2147217396
When an app is running under Graphics Diagnostics, the Capture the next rendered frame button is enabled.
Maybe this document would be helpful for you:
https://msdn.microsoft.com/en-us/library/hh708964.aspx
In addition, since it is related to the specific Games app, to really help you resolve this issue, if still no help, I suggest you post this issue to the Xbox site which has his own supported forums:
http://xboxforums.create.msdn.com/forums/76.aspx
I think you could get more dedicated support there.
Sincerely,
Jack
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